Chemists welcome the newest and heaviest elements yet to the Periodic Table
Elements 114 and 116 have been officially added to the periodic table, becoming its heaviest members yet. They both exist for less than a second before decaying into lighter atoms, but they bring researchers a step closer to making even heavier elements that are predicted to be stable for decades or longer, forming a fabled “island of stability” in the periodic table.
Evidence for the two elements has been mounting for years. They were finally given official status as new elements on Wednesday, after a three-year review by the Joint Working Party on Discovery of Elements (JWP), a committee of scientists from the International Union of Pure and Applied Chemistry (IUPAC) and the International Union of Pure and Applied Physics(IUPAP).
Several teams have claimed to have produced element 114, starting in 1999. But the committee decided that a series of experiments reported by a collaboration of two teams in 2004 and 2006 provided the first convincing evidence. The same series of experiments is credited with producing evidence of element 116.
Slammed together
One of the collaborating groups was led by Yuri Oganessian at the Joint Institute for Nuclear Research (JINR) in Dubna, Russia, and the other by Ken Moody at the Lawrence Livermore National Laboratory in California.
The researchers forged the new heavy elements by slamming together the nuclei of lighter atoms at an accelerator at JINR. They made element 116 by bombarding targets made of the radioactive element curium, which has 96 protons in its nucleus, with calcium nuclei, which have 20 protons.
Nuclei of element 116 lasted only a few milliseconds before spitting out an alpha particle made of two protons and two neutrons and thereby decaying into nuclei of element 114. The team also made element 114 directly by firing calcium nuclei at plutonium targets, which have 94 protons in their nuclei.
Gone too soon
Element-114 nuclei decayed after about half a second into copernicium, which contains 112 protons, and is itself a very recent addition to the periodic table, having officially joined in 2009. It was the pattern of time intervals between these decays, along with the energy of the alpha particles produced, that clinched the case for the elements’ creation.
So what are elements 114 and 116 like? Unfortunately, their properties are still murky because the quantities produced were too small and existed too fleetingly for scientists to measure their chemical behaviour, such as what other elements they tend to react with.
“The lifetimes of these things have to be reasonably long so you can study the chemistry – meaning, pushing a minute,” says Paul Karol of Carnegie Mellon University in Pittsburgh, who chaired the committee that approved the new elements.
‘Not too weird’
As yet, the elements have no names. Their discoverers will get a chance to offer suggestions that another IUPAC committee will consider. “As long as it’s not something really weird, they will probably say it’s fine,” Karol told New Scientist.
The committee also considered discovery claims for elements 113, 115, and 118, but said in its report that the evidence it reviewed was not yet strong enough to warrant their addition to the periodic table.
Elements found to date at this extreme end of the table are ephemeral, but nuclear theorists suspect a class of super-heavy atoms could live for decades or longer and might boast useful new chemical properties.
Karol says the discovery of elements 114 and 116 is exciting because it is a step towards this island of stability, which some predict may be centred on nuclei with 120 or 126 protons. “It’s getting closer and closer,” Karol says.
Journal reference: Pure and Applied Chemistry, DOI: 10.1351/PAC-REP-10-05-01
via Heaviest elements yet join periodic table – physics-math – 03 June 2011 – New Scientist.
